Genesis 25:26
"And after that came his brother out, and his hand took hold on Esau’s heel; and his name was called Jacob: and Isaac was threescore years old when she bare them."
Cross References (ranked by relevance)
Genesis 27:36
And he said, Is not he rightly named Jacob? for he hath supplanted me these two times: he took away my birthright; and, behold, now he hath taken away my blessing. And he said, Hast thou not reserved a blessing for me?
Hosea 12:3
He took his brother by the heel in the womb, and by his strength he had power with God: